Effect of glucuronic acid on inducing self-assembly of Au nanoflowers@glucuronic acid on carbon cloth for non-enzymatic glucose sensing

作者全名："Yuwen, T.; Zou, H.; Xu, S.; Wu, C.; Peng, Q.; Shu, D.; Yang, X.; Wang, Y.; Yu, C.; Fan, J.; Zhang, Y.; Zang, G."

作者地址："[Yuwen, T.; Xu, S.; Wu, C.; Peng, Q.; Shu, D.; Yang, X.; Wang, Y.; Yu, C.; Fan, J.; Zhang, Y.; Zang, G.] Chongqing Med Univ, Inst Life Sci, Chongqing, Peoples R China; [Yuwen, T.; Xu, S.; Wu, C.; Peng, Q.; Shu, D.; Yang, X.; Wang, Y.; Yu, C.; Fan, J.; Zhang, Y.; Zang, G.] Chongqing Med Univ, Lab Tissue & Cell Biol, Lab Teaching & Management Ctr, Chongqing 400016, Peoples R China; [Zang, G.] Jinfeng Lab, Chongqing 401329, Peoples R China; [Zou, H.] Chongqing Inst Food & Drug Control, Chongqing 401121, Peoples R China"

通信作者："Zhang, Y; Zang, G (通讯作者)，Chongqing Med Univ, Inst Life Sci, Chongqing, Peoples R China.; Zhang, Y; Zang, G (通讯作者)，Chongqing Med Univ, Lab Tissue & Cell Biol, Lab Teaching & Management Ctr, Chongqing 400016, Peoples R China.; Zang, G (通讯作者)，Jinfeng Lab, Chongqing 401329, Peoples R China."

来源：MATERIALS TODAY CHEMISTRY

ESI学科分类：　

WOS号：WOS:000992771400001

JCR分区：Q1

影响因子：6.7

年份：2023

卷号：29

期号：　

开始页：　

结束页：　

文献类型：Article

关键词：Electrochemical sensor; Non -enzymatic sensor; Gold catalyst; Electrodeposition; {110} facet

摘要："Natural materials' structural variation boosts their performance. Therefore, the precise manipulation of the structure and properties of nanomaterials by self-assembly is a topic of great interest. Here, a selfassembly of glucuronic acid (GlcA)-coated Au nanoflowers (NFs) on flexible carbon cloth (SAAuNFs@GlcA/CC) for non-enzyme electrochemical glucose detection was fabricated through the sequential deposition of gold and GlcA. The SA-AuNFs@GlcA/CC exhibits more highly exposed nanoedges than the normal AuNFs/CC without GlcA surface deposition, which may change the stereotyped traditional negative hypotheses of GlcA in glucose electrocatalysis. Notably, the unique {110} facets of Au atop the amino group grafted-CC were found in the SA-AuNFs@GlcA/CC, significantly improving the sensor's catalytic performance. The highly exposed nanoedges and unique {110} facets of SA-AuNFs@GlcA were systematically evaluated by scanning electron microscopy, transmission electron microscopy, and other electrochemical characterization tools. The SA-AuNFs@GlcA/CC exhibits excellent performance in glucose detection, including a wide linear range (5 mM-42 mM), a low limit of detection (5 mM, S/N 1/4 3), high detection selectivity, good stability, and reproductivity. The sensor successfully detected glucose in human sweat samples and beverages in real time. Thus, this simple and green manufacturing method could be used as a novel strategy for glucose monitoring in biological and food samples. (c) 2023 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/)."

基金机构："Foundation Chongquing, Chongqing, China [jfkyjf202203001]; Natural Science Foundation of Chongqing [cstc2020jcyj-msxmX0330, cstc2021jsyj- yzysbA0057]; Project of Tutorial System of Medical [LTMCMTS201913, LTMCMTS202111]; Proj- ect of Scientific Research and Innovative Experiment for College Student in Chongqing Medical University [SPIEP202167]; National Project of University Students Innovation and Entrepreneurship Training Program [S202010631016]"

基金资助正文："This work was supported by grants the Foundation Chongquing, Chongqing, China (jfkyjf202203001) ; the Natural Science Founda- tion of Chongqing (cstc2020jcyj-msxmX0330, cstc2021jsyj- yzysbA0057) ; the Project of Tutorial System of Medical Under- graduate in Lab Teaching & Management Center in Chongqing Medical University (LTMCMTS201913, LTMCMTS202111) , the Proj- ect of Scientific Research and Innovative Experiment for College Student in Chongqing Medical University (SPIEP202167) , and the National Project of University Students Innovation and Entrepreneurship Training Program (S202010631016) ."