Recent advances on carbon nitride-based photocatalysts for organic transformations in aqueous media

作者全名："Zhou, Pengfei; Cai, Yunfei; Tang, Yurong"

作者地址："[Zhou, Pengfei] Chongqing Med Univ, Coll Pharm, Chongqing 400016, Peoples R China; [Cai, Yunfei; Tang, Yurong] Chongqing Univ, Sch Chem & Chem Engn, Chongqing Key Lab Theoret & Computat Chem, Chongqing 400044, Peoples R China"

通信作者："Cai, YF; Tang, YR (通讯作者)，Chongqing Univ, Sch Chem & Chem Engn, Chongqing Key Lab Theoret & Computat Chem, Chongqing 400044, Peoples R China."

来源：ORGANIC CHEMISTRY FRONTIERS

ESI学科分类：CHEMISTRY

WOS号：WOS:001260048900001

JCR分区：Q1

影响因子：5.4

年份：2024

卷号：11

期号：16

开始页：4624

结束页：4638

文献类型：Review

关键词：　

摘要："In recent years, carbon nitride-based photocatalysts have garnered significant attention for their role in facilitating organic transformations. As a solid-state sensitizer material, carbon nitride exhibits promising properties as a heterogeneous photocatalyst, making it suitable for a variety of organic reactions. Notably, its stability, water compatibility, and recoverability render it particularly appealing for organic transformations conducted in aqueous environments. Leveraging abundant and non-toxic water as a solvent aligns with green synthetic principles, promoting sustainable development. This review encompasses a range of organic transformations, including C-H functionalization, oxidation using oxygen, hydrogenation, and related sequential reactions, as well as cross-couplings conducted in aqueous media. Additionally, reactions employing water or heavy water as reactants to provide protons (or deuterium), electrons, and hydroxy groups are discussed. We anticipate that this summary will serve as a valuable resource for future studies aimed at advancing sustainable and environmentally friendly organic synthesis using carbon nitride photocatalysts. This review highlights recent advancements in photocatalytic organic transformations in aqueous media employing the water-compatible solid-state sensitizer carbon nitride and its derivatives as catalysts."

基金机构："Chongqing Medical University Start-Up Fund [R13033]; National Natural Science Foundation of China [22371023]; National Natural Science Foundation of Chongqing [CSTB2022NSCQ-MSX1032, CSTB2022NSCQ-MSX1105]"

基金资助正文："We are grateful for the financial support from the Chongqing Medical University Start-Up Fund (R13033 to Pengfei Zhou), the National Natural Science Foundation of China (Grant No. 22371023), and the National Natural Science Foundation of Chongqing (CSTB2022NSCQ-MSX1032 and CSTB2022NSCQ-MSX1105). We thank the Analytical and Testing Centre of Chongqing University for assistance."